1,3-Butadiene
Data at NIST subscription sites:
NIST subscription sites provide data under theNIST Standard ReferenceData Program, but require an annual fee to access.The purpose of the fee is to recover costs associatedwith the development of data collections included insuch sites. Your institution may already be a subscriber.Follow the links above to find out more about the datain these sites and their terms of usage.
Go To: Top, References, Notes / Error Report
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Constant pressure heat capacity of gas
| Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
|---|
| 35.09 | 50. | Thermodynamics Research Center, 1997 | p=1 bar. Recommended values are in excellent agreement with experiment and other statistically calculated values [ Sverdlov L.M., 1962, Compton D.A.C., 1976]. Discrepancies with earlier calculations [ Aston J.D., 1946] and [ Godnev I., 1947] amount to 4.7 and 2.7 J/mol*K, respectively, in S(T) and 3.6 and 2.4 J/mol*K in Cp(T).; GT |
| 41.31 | 100. |
| 48.28 | 150. |
| 57.14 | 200. |
| 73.70 | 273.15 |
| 79.81 | 298.15 |
| 80.27 | 300. |
| 103.44 | 400. |
| 122.09 | 500. |
| 136.51 | 600. |
| 148.04 | 700. |
| 157.67 | 800. |
| 165.92 | 900. |
| 173.10 | 1000. |
| 179.36 | 1100. |
| 184.84 | 1200. |
| 189.64 | 1300. |
| 193.85 | 1400. |
| 197.54 | 1500. |
Go To: Top, Gas phase thermochemistry data, Notes / Error Report
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Prosen, Maron, et al., 1951
Prosen, E.J.; Maron, F.W.; Rossini, F.D.,Heats of combustion, formation, and insomerization of ten C4 hydrocarbons,J. Res. NBS, 1951, 46, 106-112. [all data]
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,Heats of formation and combustion of 1,3-butadiene and styrene,J. Res. NBS, 1945, 34, 59-63. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Sverdlov L.M., 1962
Sverdlov L.M.,Calculation of thermodynamic functions of gaseous 1,3-butadiene from spectroscopic data,Zh. Fiz. Khim., 1962, 36, 2765-2767. [all data]
Compton D.A.C., 1976
Compton D.A.C.,Conformations of conjugated hydrocarbons. Part 1. A spectroscopic and thermodynamic study of buta-1,3-diene and 2-methylbuta-1,3-diene,J. Chem. Soc. Perkin Trans. 2, 1976, 1666-1671. [all data]
Aston J.D., 1946
Aston J.D.,Thermodynamic properties of gaseous 1,3-butadiene and normal butenes above 25 C. Equilibria in the system 1,3-butadiene, n-butenes, and n-butane,J. Chem. Phys., 1946, 14, 67-79. [all data]
Godnev I., 1947
Godnev I.,Thermodynamic functions of divinyl and equilibrium constant of formation of divinyl from alcohol,Zh. Fiz. Khim., 1947, 21, 799-809. [all data]
Go To: Top, Gas phase thermochemistry data, References
- Symbols used in this document:
- Data from NIST Standard Reference Database 69:NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST)uses its best efforts to deliver a high quality copy of theDatabase and to verify that the data contained therein havebeen selected on the basis of sound scientific judgment.However, NIST makes no warranties to that effect, and NISTshall not be liable for any damage that may result fromerrors or omissions in the Database.
- Rate our products and services. Take the NIST MeasurementServices Customer Satisfaction Survey.
- If you believe that this page may contain an error, pleasefill out the error report formfor this page.
© 2011 by the U.S.Secretary of Commerce on behalf of the United States of America.All rights reserved.
Copyright for NIST Standard Reference Data is governed bythe Standard Reference Data Act.
If you have comments or questions about this site, pleasecontact us.
1,3-Butadiene
Data at NIST subscription sites:
NIST subscription sites provide data under theNIST Standard ReferenceData Program, but require an annual fee to access.The purpose of the fee is to recover costs associatedwith the development of data collections included insuch sites. Your institution may already be a subscriber.Follow the links above to find out more about the datain these sites and their terms of usage.
Go To: Top, References, Notes / Error Report
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Constant pressure heat capacity of gas
| Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
|---|
| 35.09 | 50. | Thermodynamics Research Center, 1997 | p=1 bar. Recommended values are in excellent agreement with experiment and other statistically calculated values [ Sverdlov L.M., 1962, Compton D.A.C., 1976]. Discrepancies with earlier calculations [ Aston J.D., 1946] and [ Godnev I., 1947] amount to 4.7 and 2.7 J/mol*K, respectively, in S(T) and 3.6 and 2.4 J/mol*K in Cp(T).; GT |
| 41.31 | 100. |
| 48.28 | 150. |
| 57.14 | 200. |
| 73.70 | 273.15 |
| 79.81 | 298.15 |
| 80.27 | 300. |
| 103.44 | 400. |
| 122.09 | 500. |
| 136.51 | 600. |
| 148.04 | 700. |
| 157.67 | 800. |
| 165.92 | 900. |
| 173.10 | 1000. |
| 179.36 | 1100. |
| 184.84 | 1200. |
| 189.64 | 1300. |
| 193.85 | 1400. |
| 197.54 | 1500. |
Go To: Top, Gas phase thermochemistry data, Notes / Error Report
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Prosen, Maron, et al., 1951
Prosen, E.J.; Maron, F.W.; Rossini, F.D.,Heats of combustion, formation, and insomerization of ten C4 hydrocarbons,J. Res. NBS, 1951, 46, 106-112. [all data]
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,Heats of formation and combustion of 1,3-butadiene and styrene,J. Res. NBS, 1945, 34, 59-63. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Sverdlov L.M., 1962
Sverdlov L.M.,Calculation of thermodynamic functions of gaseous 1,3-butadiene from spectroscopic data,Zh. Fiz. Khim., 1962, 36, 2765-2767. [all data]
Compton D.A.C., 1976
Compton D.A.C.,Conformations of conjugated hydrocarbons. Part 1. A spectroscopic and thermodynamic study of buta-1,3-diene and 2-methylbuta-1,3-diene,J. Chem. Soc. Perkin Trans. 2, 1976, 1666-1671. [all data]
Aston J.D., 1946
Aston J.D.,Thermodynamic properties of gaseous 1,3-butadiene and normal butenes above 25 C. Equilibria in the system 1,3-butadiene, n-butenes, and n-butane,J. Chem. Phys., 1946, 14, 67-79. [all data]
Godnev I., 1947
Godnev I.,Thermodynamic functions of divinyl and equilibrium constant of formation of divinyl from alcohol,Zh. Fiz. Khim., 1947, 21, 799-809. [all data]
Go To: Top, Gas phase thermochemistry data, References
- Symbols used in this document:
- Data from NIST Standard Reference Database 69:NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST)uses its best efforts to deliver a high quality copy of theDatabase and to verify that the data contained therein havebeen selected on the basis of sound scientific judgment.However, NIST makes no warranties to that effect, and NISTshall not be liable for any damage that may result fromerrors or omissions in the Database.
- Rate our products and services. Take the NIST MeasurementServices Customer Satisfaction Survey.
- If you believe that this page may contain an error, pleasefill out the error report formfor this page.
© 2011 by the U.S.Secretary of Commerce on behalf of the United States of America.All rights reserved.
Copyright for NIST Standard Reference Data is governed bythe Standard Reference Data Act.
If you have comments or questions about this site, pleasecontact us.